N-bromosuccinimide (NBS) is used as a highly specific bromination agent both in free-radical
substitutions and in electrophilic additions of unsaturated systems, because releases small quantities of bromine.
NBS is used as a substitute for Br2 in these cases since Br2 tends to react with double bonds to form dibromides. The advantage of NBS is that it provides a low-level concentration of Br2, and bromination of the double bond doesn't compete as much.
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