Platinum oxide is widely used as a hydrogenation catalyst in organic synthesis (refer to catalytic hydrogenation reaction).
However latinum black generated from the hydrogen reduction of platinum dioxide in the reaction acts as the actual catalyst.
Ultrasmall platinum nanoparticles on carbon catalyst supports undergo oxidation in ambient air. A systematic survey of carbon supports with controlled pore structures was conducted to isolate the effect of pore structure on particle size and resistance to oxidation. It was found that carbon supports with higher microporosity gave larger metal particles at high metal weight loadings whereas the particle sizes remained independent of pore size at low weight loadings.
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