Barium bromide is a precursor to chemicals used in photography and to other bromides. Historically, barium bromide was used to purify radium in a process of fractional crystallization devised by Marie Curie.
Barium bromide crystallizes from concentrated aqueous solution in its dihydrate , BaBr2·2H2O. Heating this dihydrate to 120 °C gives the anhydrous salt.
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